GS CALTEX — BUSINESS CH.03 / OLEFINSKREN中日

GS CALTEX BUSINESS — CHAPTER 03

OLEFINS

Using diverse feedstock including naphtha, LPG and refinery off-gas
to produce 900,000 tons of ethylene a year.

GS Caltex produces basic petrochemical products like ethylene and propylene through MFC (Mixed Feed Cracker), which can use a wide range of feedstocks — not just naphtha, but also LPG and refinery off-gas. By flexibly drawing on diverse feedstocks, we strengthen feedstock competitiveness and build synergy between refining and petrochemicals.

ORIGIN

Why do we call it
"Olefin"?

The name olefin comes from the observation that ethylene reacts with chlorine to form an oily liquid.

Today, olefin refers to a hydrocarbon with a carbon-carbon double bond (C=C), with ethylene and propylene as its leading examples. Their high reactivity makes them a foundational feedstock for a wide range of chemical products and plastic materials.

01 — MIXED FEED

Using diverse feedstock
flexibly

MFC can use liquid naphtha along with LPG and refinery off-gas as feedstock. This gives us more flexibility in feedstock selection and, through its link to the refining process, greater feedstock competitiveness.

01 — CRACKING

Cracking hydrocarbons
with intense heat

Hydrocarbons such as naphtha and LPG are thermally cracked at high temperature into smaller molecules. Quenching, compression and separation follow, yielding ethylene, propylene and other basic petrochemical products.

01 — OLEFINS

Producing ethylene, propylene
and other basic petrochemicals

Ethylene and propylene are the leading olefins, each carrying a carbon double bond (C=C). Their high reactivity makes them the foundational feedstock for polyethylene (PE), polypropylene (PP) and many other petrochemical products.

02 — OUTPUT

The main
products from MFC

ETHYLENEFEEDSTOCK FOR MANY PETROCHEMICALS

Ethylene

0K tons / yr

Used as a basic feedstock for a wide range of petrochemical products, including polyethylene (PE), polystyrene (PS), PVC and EVA.

PEPSPVCEVA
PROPYLENEFEEDSTOCK FOR PP AND MORE

Propylene

0K tons / yr

Used as feedstock for polypropylene (PP), compound resin, propylene oxide (PO) and acrylonitrile (AN).

PPCompound resinPOAN
MIXED C4FEEDSTOCK FOR RUBBER AND RESINS

Mixed C4

0K tons / yr

Used to produce butadiene, the feedstock for synthetic rubber, ABS, nylon and other materials.

Synthetic rubberABSNylon
PYGASFEEDSTOCK FOR AROMATICS

Pyrolysis Gasoline

0K tons / yr

Used as feedstock for producing aromatics such as benzene, toluene and xylene.

BenzeneTolueneXylene→ CH.02 Aromatics

03 — FEED

The competitiveness of MFC's diverse feedstocks

NaphthaLIQUID
0K tons/yr (max)
Naphtha produced in refining is used as a main feedstock for MFC.
LPGGAS
0K tons/yr (max)
LPG such as propane (C3) can also be used as feedstock for MFC.
Refinery off-gasFCC OFF-GAS
0K tons/yr (max)
Off-gas from the FCC unit is also used as feedstock for MFC, strengthening the link between refining and petrochemicals.

04 — MFC · COMPETITIVENESS

Extending competitiveness
from refining into petrochemicals

GS Caltex invested approximately ₩2.7 trillion to build MFC at the Yeosu complex, completed in November 2022.

MFC secured an annual ethylene capacity of 900,000 tons and, by linking refining and petrochemical processes, broadened both feedstock use and the business portfolio.

Ethylene and propylene made at MFC go through polymerization and other processes to become polyethylene and polypropylene and other polymers. The next chapter follows olefins into the polymer business, which leads on to automotive parts, appliances, packaging and countless other everyday and industrial materials.